Difference between revisions of "Ammonia fibre expansion"

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Ammonia fiber expansion (AFEX) is a thermochemical pretreatment that uses volatile ammonia as the main reactant for cellulosic biomass pretreatment. AFEX pretreatment increases the accessibility of polysaccharides to enzymes for hydrolysis into fermentable sugars. These released sugars can be converted into fuels and chemicals in a biorefinery. AFEX offers several advantages over other pretreatments, which include near complete recovery of the pretreatment chemical (ammonia), nutrient addition for microbial growth through the remaining ammonia on pretreated biomass, and not requiring a washing step during the process which facilitates high solid loading hydrolysis.
{{Infobox technology|Category=[[Pre-processing]] ([[Pre-processing#Thermochemical_processes_and_technologies|Thermochemical processes and technologies]])}}
<onlyinclude>Ammonia fibre expansion (AFEX) is a thermochemical pretreatment that uses volatile ammonia as the main reactant for cellulosic biomass pretreatment. AFEX pretreatment increases the accessibility of polysaccharides to enzymes for hydrolysis into fermentable sugars. These released sugars can be converted into fuels and chemicals in a biorefinery. AFEX offers several advantages over other pretreatments, which include near complete recovery of the pretreatment chemical (ammonia), nutrient addition for microbial growth through the remaining ammonia on pretreated biomass, and not requiring a washing step during the process which facilitates high solid loading hydrolysis.</onlyinclude>


== Feedstock ==
== Feedstock ==
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=== Origin and composition ===
=== Origin and composition ===
Agricultural residues and energy crops
Agricultural residues and energy crops
=== Pre-treatment ===


== Process and technologies ==
== Process and technologies ==
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== Product ==
== Product ==
After AFEX hydrolysis of lignocellulosic biomass, fermentable sugars are produced. These fermentable sugars can subsequently be converted into fuels (e.g., bioethanol) and chemicals.
After AFEX hydrolysis of lignocellulosic biomass, fermentable sugars are produced. These fermentable sugars can subsequently be converted into fuels (e.g., bioethanol) and chemicals.
=== Post-treatment ===


== Technology providers ==
== Technology providers ==
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{| class="wikitable sortable mw-collapsible"
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! class="cd-text-darkgreen" style="vertical-align:{{{va|bottom}}}"| Company name
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! class="cd-text-darkgreen" style="vertical-align:{{{va|bottom}}}"| Technology name
! class="cd-text-darkgreen" style="vertical-align:{{{va|bottom}}}"| Technology name
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| [[Help:Article content of technology pages#Company_1|Company 1]]
| [[Ammonia fibre expansion#Michigan Biotechnology Institute .28MBI.29|Michigan Biotechnology Institute (MBI)]]
| [Country HQ location]
| USA
| [Technology category (if different sub-categories are defined this has to be specified here, the available categories can be found on each technology page under the chapter [[Help:Article content of technology pages#Process_and_technologies|Process and technologies]])]
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| [Technology name (the "branded name" or the usual naming from company side)]
| packed bed AFEX
| [4-9]
| 4-5
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| 1000
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|100-140
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|0.25-0.5
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| [Country HQ location]
| [(if different sub-categories are defined this has to be specified here, the available categories can be found on each technology page under the chapter [[Help:Article content of technology pages#Process_and_technologies|Process and technologies]])]
| [Technology name (the "branded name" or the usual naming from company side)]
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=== Michigan Biotechnology Institute (MBI) ===
{{Infobox provider-ammonia fibre expansion|Company=Michigan Biotechnology Institute|Country=USA|Technology name=packed bed AFEX|Technology category=Thermochemical processes|Webpage=http://www.mbi.org/|TRL=4-5|Capacity=1.000|Temperature=100-140|Residence time=15-30|Feedstock=Agricultural residues}}
== Open access pilot and demo facility providers ==
Currently no providers have been identified.
== Patents ==
Currently no patents have been identified.


== References ==
== References ==
[[Category:Pre-processing]]
[[Category:Technologies]]

Latest revision as of 10:48, 7 March 2023

Technology
21-04-27 Tech4Biowaste rect-p.png
Technology details
Name:
Category: Pre-processing (Thermochemical processes and technologies)
Feedstock:
Product:

Ammonia fibre expansion (AFEX) is a thermochemical pretreatment that uses volatile ammonia as the main reactant for cellulosic biomass pretreatment. AFEX pretreatment increases the accessibility of polysaccharides to enzymes for hydrolysis into fermentable sugars. These released sugars can be converted into fuels and chemicals in a biorefinery. AFEX offers several advantages over other pretreatments, which include near complete recovery of the pretreatment chemical (ammonia), nutrient addition for microbial growth through the remaining ammonia on pretreated biomass, and not requiring a washing step during the process which facilitates high solid loading hydrolysis.

Feedstock

Origin and composition

Agricultural residues and energy crops

Pre-treatment

Process and technologies

Process

During AFEX pretreatment, liquid ammonia is added to the biomass under moderate pressure (100 to 400 psi) and temperature (70 to 200°C) before rapidly releasing the pressure. Major process parameters are the temperature of the reaction, residence time, ammonia loading, and water loading. The process decrystallises the cellulose, hydrolyses hemicellulose, removes and depolymerises lignin, and increases the size and number of micropores in the cell wall. As a result, the rate of enzymatic hydrolysis increases significantly.[1]

Technologies

Product

After AFEX hydrolysis of lignocellulosic biomass, fermentable sugars are produced. These fermentable sugars can subsequently be converted into fuels (e.g., bioethanol) and chemicals.

Post-treatment

Technology providers

Technology comparison
Company name Country Technology subcategory Technology name TRL Capacity [kg/h] Processable mass [kg] Pressure [bar] Temperature [°C] Ammonia loading [L] Water loading [L] Residence time [h] Feedstock: Food waste Feedstock: Garden & park waste
Michigan Biotechnology Institute (MBI) USA - packed bed AFEX 4-5 1000 - - 100-140 - - 0.25-0.5

Michigan Biotechnology Institute (MBI)

Ammonia fibre expansion provider
General information
Company: Michigan Biotechnology Institute 21-04-27 Tech4Biowaste rect-p.png
Country: USA
Contact:
Webpage: http://www.mbi.org/
Technology and process details
Technology name: packed bed AFEX Technology category: Pre-processing (Thermochemical processes and technologies)
TRL: 4-5 Capacity: 1.000 kg·h-1
Ammonia loading: L Pressure: bar
Residence time: 15-30 min Temperature: 100-140 °C
Other:
Feedstock and product details
Feedstock: Agricultural residues Product:

Open access pilot and demo facility providers

Currently no providers have been identified.

Patents

Currently no patents have been identified.

References

  1. Mosier N., Wyman C., Dale BE., Elander R., Lee YY., Holtzappel M., Ladisch M., 2005: Features of promising technologies for pretreatment of lignocellulosic biomass. Bioresource Technology, Vol. 96, 673-686. doi: https://doi.org/