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For residual flows from the food industry, crop residues and manure, thermal and chemical pre-treatments are mainly applied. The most important effects of thermal pre-treatment are: reducing particle size, increasing solubility and improve the biodegradability. Additional advantages of thermal pre-treatment are: (1) higher loading of the digester is possible, (2) lower viscosity of the treated material which results in lower energy input for mixing the digester, (3) improved dewaterability of digestate and (4) sanitised product. | For residual flows from the food industry, crop residues and manure, thermal and chemical pre-treatments are mainly applied. The most important effects of thermal pre-treatment are: reducing particle size, increasing solubility and improve the biodegradability. Additional advantages of thermal pre-treatment are: (1) higher loading of the digester is possible, (2) lower viscosity of the treated material which results in lower energy input for mixing the digester, (3) improved dewaterability of digestate and (4) sanitised product. | ||
The following pre-treatments may be considered : | |||
* [[Particle filtering]] | |||
* [[Sizing]] (e.g. chipping, grinding) | |||
* Thermal pre-treatment | |||
== Process and technologies == | == Process and technologies == | ||
=== Process === | === Process === | ||
There are three basic anaerobic digestion processes, namely psychrophilic, mesophilic, and thermophilic, which take place over different temperature ranges. Psychrophilic digestion is a low temperature (<20°C) process. Mesophilic digestion takes place between 20 and 45°C, which can take a month or two to complete, and thermophilic digestion between 45 and 65°C, which is faster, but its micro-organisms are more sensitive. The majority of the agricultural biogas plants are operated at mesophilic temperatures. Thermophilic temperatures are applied mainly in large-scale centralised biogas plants with co-digestion<ref>{{Cite web|year=2021|title=Anaerobic digestion|e-pub date=2021|date accessed=6/9/2021|url=https://www.eubia.org/cms/wiki-biomass/anaerobic-digestion/}}</ref>. The process of anaerobic digestion takes place through four successive stages: | There are three basic anaerobic digestion processes, namely psychrophilic, mesophilic, and thermophilic, which take place over different temperature ranges. Psychrophilic digestion is a low temperature (<20°C) process. Mesophilic digestion takes place between 20 and 45°C, which can take a month or two to complete, and thermophilic digestion between 45 and 65°C, which is faster, but its micro-organisms are more sensitive. The majority of the agricultural biogas plants are operated at mesophilic temperatures. Thermophilic temperatures are applied mainly in large-scale centralised biogas plants with co-digestion<ref>{{Cite web|year=2021|title=Anaerobic digestion|e-pub date=2021|date accessed=6/9/2021|url=https://www.eubia.org/cms/wiki-biomass/anaerobic-digestion/}}</ref>. The process of anaerobic digestion takes place through four successive stages: hydrolysis, fermentation, acetogenesis, and methanogenesis.<ref>{{Cite journal|author=Junye Wang|year=2014|title=Decentralized biogas technology of anaerobic digestion and farm ecosystem: opportunities and challenges|journal=Fronties in Energy Research|volume=2|page=|doi=10.3389/fenrg.2014.00010}}</ref> In the hydrolysis step, the feedstock is broken down into soluble substrates (e.g., sugar and amino acids) by enzymes. Fermentation involves the conversion of sugar, amino acids, and fatty acids into ammonia, organic acids, hydrogen (H<sub>2</sub>) and CO<sub>2</sub>. In the acetogenesis step, volatile fatty acids are broken down into acetic acids, CO<sub>2</sub> and H<sub>2</sub>. Finally, methanogenesis step converts acetate, formaldeyde, and H<sub>2</sub> to CH<sub>4</sub> and water<ref>{{Cite journal|author=Jay N. Meegoda, Brian Li, Kush Patel, Lily B. Wang|year=2018|title=A review of the Processes, Parameters, and Optimization of Anaerobic Digestion|journal=International Journal of Environmental Research and Public Health|volume=15|page=|doi=10.3390/ijerph15102224}}</ref>. | ||
[[File:Anaerobic stages.png|thumb|Simplified scheme of pathways in anaerobic digestion (not own work)]] | [[File:Anaerobic stages.png|thumb|Simplified scheme of pathways in anaerobic digestion (not own work)]] | ||