Difference between revisions of "Ionic liquids"

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Revision as of 12:59, 30 August 2021

Ionic liquids are organic salts that are liquid at room temperature. Because they are salts, they show no volatility. Moreover, they show a high thermal stability. Together this allows for them to be used as green solvents as alternatives to volatile organic compounds. These properties can be used in the pre-treatment of lignocellulosic material by dissolving the material and separating the lignin.^[1]

Feedstock

Ionic liquids are capable of dissolving lignocellulosic biomass. Examples inclue corn stalks, rice straw, bagasse, pine wood, and spruce wood.^[1]

Process and technologies

Ionic liquids have been shown to dissolve cellulose, which can decrease its crystalinity and therefore make it more accessible for further processing. Moreover, a full dissolution of lignocellulosic biomass can be used to extract the lignin. The technology can also be combined with hydrolysis to make the cellulose available as sugars for further processing.^[1]

Product

The final product of the process depends on the exact combination of technologies. Generally, a large part of the lignin can be extracted. The resulting lignin is one of the products, the other begin the remaining lignocellulosic material, where the cellulose is more easily available for further processing.

Technology providers

[space for technology comparison]

Currently no examples yet.

Patents

Currently no patents have been identified yet.

References

↑ ^a ^b ^c Sang Hyun Lee, Thomas V. Doherty, Robert J. Linhardt, Jonathan S. Dordick, 2009-04-01: Ionic liquid-mediated selective extraction of lignin from wood leading to enhanced enzymatic cellulose hydrolysis. Biotechnology and Bioengineering, Vol. 102, (5), 1368–1376. doi: https://doi.org/10.1002/bit.22179

[:0-1] Sang Hyun Lee, Thomas V. Doherty, Robert J. Linhardt, Jonathan S. Dordick, 2009-04-01: Ionic liquid-mediated selective extraction of lignin from wood leading to enhanced enzymatic cellulose hydrolysis. Biotechnology and Bioengineering, Vol. 102, (5), 1368–1376. doi: https://doi.org/10.1002/bit.22179

[1]

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+'''Ionic liquids''' are organic salts that are liquid at room temperature. Because they are salts, they show no volatility. Moreover, they show a high thermal stability. Together this allows for them to be used as green solvents as alternatives to volatile organic compounds. These properties can be used in the pre-treatment of lignocellulosic material by dissolving the material and separating the lignin.<ref name=":0">{{Cite journal|title=Ionic liquid-mediated selective extraction of lignin from wood leading to enhanced enzymatic cellulose hydrolysis|year=2009-04-01|author=Sang Hyun Lee, Thomas V. Doherty, Robert J. Linhardt, Jonathan S. Dordick|journal=Biotechnology and Bioengineering|volume=102|issue=5|page=1368–1376|doi=10.1002/bit.22179}}</ref>
-'''Hydrolysis''' (/haɪˈdrɒlɪsɪs/; from Ancient Greek ''hydro-'' 'water', and ''lysis'' 'to unbind') is a chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile.<ref>{{Cite web|year=2002|title=Hydrolysis|e-pub date=2002|date accessed=2021|url=https://en.wikipedia.org/wiki/Hydrolysis|Author=Wikipedia}}</ref> In lignocellulosic biomass, the cellulose and hemicellulose breaks down into individual sugars, where hemicellulose is easier to hydrolyse than cellulose.<ref>{{Cite journal|title=Dilute acid hydrolysis of lignocellulosic biomass|year=2010-01-15|author=P. Lenihan, A. Orozco, E. O’Neill, M.N.M. Ahmad, D.W. Rooney, G.M. Walker|journal=Chemical Engineering Journal|volume=156|issue=2|page=395–403|doi=10.1016/j.cej.2009.10.061}}</ref> The result of hydrolysing hemicellulose and cellulose is sugars (glucose, xylose, mannose, and galactose) and organic acids (formic acid and acetic acid).<ref>{{Cite journal|title=Acid Hydrolysis of Lignocellulosic Biomass: Sugars and Furfurals Formation|year=2020-04-17|author=Katarzyna Świątek, Stephanie Gaag, Andreas Klier, Andrea Kruse, Jörg Sauer, David Steinbach|journal=Catalysts|volume=10|issue=4|page=437|doi=10.3390/catal10040437}}</ref>
 ==Feedstock==
-Hydrolysis can be performed as a pretreatment on any biowaste with a high lignocellulose content. Lignocellulose is typically the nonedible part of a plant, composed of a complex of cellulose, hemi-cellulose and lignin. In order to make the celluloses available for further processing, in the form of its monomeric sugars, they can be hydrolysed. Suitable feedstocks include grasses, straw, leaves, stems, shells, manure, paper waste, and others. The ratio between cellulose, hemi-cellulose and lignin varies wildly depending on the specific feedstock.<ref name=":1">{{Cite book|author=Alessandra Verardi, Isabella De Bari, Emanuele Ricca and Vincenza Calabrò|year=2012|section_title=Hydrolysis of Lignocellulosic Biomass: Current Status of Processes and Technologies and Future Perspectives|editor=Marco Aurelio Pinheiro Lima and Alexandra Pardo Policastro Natalense|book_title=Bioethanol|publisher=IntechOpen}}</ref>
+Ionic liquids are capable of dissolving lignocellulosic biomass. Examples inclue corn stalks, rice straw, bagasse, pine wood, and spruce wood.<ref name=":0" />
 ==Process and technologies==
-Lorum ipsum.
+Ionic liquids have been shown to dissolve cellulose, which can decrease its crystalinity and therefore make it more accessible for further processing. Moreover, a full dissolution of lignocellulosic biomass can be used to extract the lignin. The technology can also be combined with [[hydrolysis]] to make the cellulose available as sugars for further processing.<ref name=":0" />
 ==Product==
-Lorum ipsum
+The final product of the process depends on the exact combination of technologies. Generally, a large part of the lignin can be extracted. The resulting lignin is one of the products, the other begin the remaining lignocellulosic material, where the cellulose is more easily available for further processing.
 ==Technology providers==
 [space for technology comparison]
 ===Currently no examples yet.===
 ==Patents==
-Lorum ipsum
+Currently no patents have been identified yet.
 ==References==
 <references />