Difference between revisions of "Heterogeneous catalysis"
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Heterogeneous catalysis is a catalysis in which the catalyst and the feedstock are different phases. In practice, this often means that the feedstock is a liquid or gas and the catalyst is a solid, also known as ''solid catalysis.'' | Heterogeneous catalysis is a catalysis in which the catalyst and the feedstock are different phases. In practice, this often means that the feedstock is a liquid or gas and the catalyst is a solid, also known as ''solid catalysis.'' There is a wide variety of catalytic systems and many reactions can be catalysed with a solid catalyst. Examples are [[pyrolysis]], hydro-processing, [[oxidation]], dehydration, [[hydrolysis]], (trans)esterification, and isomerisation.<ref name=":1">{{Cite journal|title=Functionalised heterogeneous catalysts for sustainable biomass valorisation|year=2018|author=Putla Sudarsanam, Ruyi Zhong, Sander Van den Bosch, Simona M. Coman, Vasile I. Parvulescu, Bert F. Sels|journal=Chemical Society Reviews|volume=47|issue=22|page=8349–8402|doi=10.1039/C8CS00410B}}</ref> Common heterogeneous catalysts are heterogeneous solid base catalysts and heterogeneous solid acid catalysts.<ref name=":0">{{Cite journal|title=A review of sustainable biodiesel production using biomass derived heterogeneous catalysts|year=2021-10-22|author=Semakula Maroa, Freddie Inambao|journal=Engineering in Life Sciences|page=elsc.202100025|doi=10.1002/elsc.202100025}}</ref> {{Infobox technology|Name=Heterogeneous catalysis|Category=Conversions|Feedstock=Wide range|Product=Wide range}} | ||
==Feedstock== | ==Feedstock== | ||
Due to the wide range of available catalysts and the large spectrum of reactions they can catalyse, the feedstock range for heterogeneous catalysis is significant. This ranges from biomass feedstocks such as lignocellulose (citation needed), lignin, cellulose, sugars, and fatty acids, to products derived from biomass, such as glycerol and furfural.<ref name=":1" /> | |||
==Process and technologies== | ==Process and technologies== | ||
A wide range of processes and technologies can make use of heterogeneous catalysts. Examples are [[pyrolysis]], hydro-processing, [[oxidation]], dehydration, [[hydrolysis]], (trans)esterification, and isomerisation.<ref name=":1" /> The most common heterogeneous catalysts are heterogeneous solid base catalysts and heterogeneous solid acid catalysts. Base catalysts have a high concentration of basic sites that ensures the catalytic activity, often from Ba, Ca, Mg, and Sr and can be mixed or doped. Soap formation is a recurring drawback of these systems. Acid catalysts get their activity either from Brønsted or Lewis acidity and are commonly zirconia, silica, zeolites or zeotype materials. Major advantages of heterogeneous catalysis is the ease of separation, recyclability and high selectivity.<ref name=":0" /> Current development for future heterogeneous catalytic systems are in metal-organic frameworks (MOFs), magnetic catalysts, and solid phase ionic liquids.<ref name=":1" /> | |||
==Product== | ==Product== | ||
Heterogeneous catalysis is widely used throughout chemistry and a plethora of products can be made. Heterogeneous catalysis is often used in the production of biodiesel<ref name=":0" />, but can also be employed in the [[pyrolysis]] process. | Heterogeneous catalysis is widely used throughout chemistry and a plethora of products can be made. Heterogeneous catalysis is often used in the production of biodiesel<ref name=":0" />, but can also be employed in the [[pyrolysis]] process or in the production of many other value added chemicals.<ref name=":1" /> | ||
==Technology providers== | ==Technology providers== | ||
[space for technology comparison] | [space for technology comparison] | ||
Revision as of 14:31, 15 November 2021
Heterogeneous catalysis is a catalysis in which the catalyst and the feedstock are different phases. In practice, this often means that the feedstock is a liquid or gas and the catalyst is a solid, also known as solid catalysis. There is a wide variety of catalytic systems and many reactions can be catalysed with a solid catalyst. Examples are pyrolysis, hydro-processing, oxidation, dehydration, hydrolysis, (trans)esterification, and isomerisation.[1] Common heterogeneous catalysts are heterogeneous solid base catalysts and heterogeneous solid acid catalysts.[2]
| Technology | |
| |
| Technology details | |
| Name: | Heterogeneous catalysis |
| Category: | Conversions |
| Feedstock: | Wide range |
| Product: | Wide range |
Feedstock
Due to the wide range of available catalysts and the large spectrum of reactions they can catalyse, the feedstock range for heterogeneous catalysis is significant. This ranges from biomass feedstocks such as lignocellulose (citation needed), lignin, cellulose, sugars, and fatty acids, to products derived from biomass, such as glycerol and furfural.[1]
Process and technologies
A wide range of processes and technologies can make use of heterogeneous catalysts. Examples are pyrolysis, hydro-processing, oxidation, dehydration, hydrolysis, (trans)esterification, and isomerisation.[1] The most common heterogeneous catalysts are heterogeneous solid base catalysts and heterogeneous solid acid catalysts. Base catalysts have a high concentration of basic sites that ensures the catalytic activity, often from Ba, Ca, Mg, and Sr and can be mixed or doped. Soap formation is a recurring drawback of these systems. Acid catalysts get their activity either from Brønsted or Lewis acidity and are commonly zirconia, silica, zeolites or zeotype materials. Major advantages of heterogeneous catalysis is the ease of separation, recyclability and high selectivity.[2] Current development for future heterogeneous catalytic systems are in metal-organic frameworks (MOFs), magnetic catalysts, and solid phase ionic liquids.[1]
Product
Heterogeneous catalysis is widely used throughout chemistry and a plethora of products can be made. Heterogeneous catalysis is often used in the production of biodiesel[2], but can also be employed in the pyrolysis process or in the production of many other value added chemicals.[1]
Technology providers
[space for technology comparison]
No technology providers identified yet.
Patents
Currently no patents have been identified yet.
References
- ↑ a b c d e Putla Sudarsanam, Ruyi Zhong, Sander Van den Bosch, Simona M. Coman, Vasile I. Parvulescu, Bert F. Sels, 2018: Functionalised heterogeneous catalysts for sustainable biomass valorisation. Chemical Society Reviews, Vol. 47, (22), 8349–8402. doi: https://doi.org/10.1039/C8CS00410B
- ↑ a b c Semakula Maroa, Freddie Inambao, 2021-10-22: A review of sustainable biodiesel production using biomass derived heterogeneous catalysts. Engineering in Life Sciences, Vol. , elsc.202100025. doi: https://doi.org/10.1002/elsc.202100025