Difference between revisions of "Ultrasonication"

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During the ultrasonication treatment, ultrasound is transmitted through any physical medium by waves that compress and stretch the molecular spacing of the medium through which it passes<ref name=":0">{{Cite book|author=Hugo Miguel Santos, Carlos Lodeiro, and José-Luis Capelo-Martínez|year=2008|section_title=The Power of Ultrasound|editor=José-Luis Capelo-Martínez|book_title=Ultrasound in Chemistry: Analytical Applications|publisher=Wiley‐VCH Verlag GmbH & Co. KGaA|ISBN=9783527319343|place=Weinheim, Germany}}</ref>. The distance between the molecules will vary as they oscillate about their mean position<ref name=":0" />. When the negative pressure is large enough, the distance between the molecules of the liquid exceeds the minimum molecular distance required to hold the liquid intact, and then the liquid breaks down and voids (cavitation bubbles) are created<ref name=":0" />.  
During the ultrasonication treatment, ultrasound is transmitted through any physical medium by waves that compress and stretch the molecular spacing of the medium through which it passes<ref name=":0">{{Cite book|author=Hugo Miguel Santos, Carlos Lodeiro, and José-Luis Capelo-Martínez|year=2008|section_title=The Power of Ultrasound|editor=José-Luis Capelo-Martínez|book_title=Ultrasound in Chemistry: Analytical Applications|publisher=Wiley‐VCH Verlag GmbH & Co. KGaA|ISBN=9783527319343|place=Weinheim, Germany}}</ref>. The distance between the molecules will vary as they oscillate about their mean position<ref name=":0" />. When the negative pressure is large enough, the distance between the molecules of the liquid exceeds the minimum molecular distance required to hold the liquid intact, and then the liquid breaks down and voids (cavitation bubbles) are created<ref name=":0" />.  


The medium for ultrasonication can be water, an organic solvent, or a dilute acid or base.<ref name=":1" /> <!-- Maybe it is easier to understand when you add figures to the text.
The medium for ultrasonication can be water, an organic solvent, or a dilute acid or base.<ref name=":1" />
[[File:Schematic of bench and industrial-scale ultrasonic liquid processors produced by Industrial Sonomechanics, LLC.jpg|alt=Schematic of bench and industrial-scale ultrasonic liquid processors|thumb|Schematic of bench and industrial-scale ultrasonic liquid processors produced by Industrial Sonomechanics, LLC]]<!-- Maybe it is easier to understand when you add figures to the text.


Some interesting links:
Some interesting links:

Revision as of 13:51, 31 January 2022

Technology
21-04-27 Tech4Biowaste rect-p.png
Technology details
Name: Ultrasonication
Category: Pretreatment
Feedstock: Biowaste
Product: Biomass (dispersed, disrupted, emulsified, extracted, homogenised)

Ultrasonication is a physical treatment to disperse, disrupt, emulsify, extract, and/or homogenise biomass via the application of ultrasonic frequencies (>20 kHz). The propagation of sound waves through the biomass results in spontaneous formation and collapse of microsized cavities. This activity produces a hot-spot effect, resulting in high temperature and pressure gradients to form locally, while the overall conditions remain ambient. This effect can be used to break down morphologies, for example for the depolymerisation of lignocellulosic biowaste.[1]

Feedstock

Composition

The requirements on the composition of the feedstock may vary since ultrasonication can be utilised at various points in the value chain of biowaste valorisation.

Pre-treatment

Ultrasonication is often the first step of the pretreatment, although initial sizing may be required.

Process and technologies

During the ultrasonication treatment, ultrasound is transmitted through any physical medium by waves that compress and stretch the molecular spacing of the medium through which it passes[2]. The distance between the molecules will vary as they oscillate about their mean position[2]. When the negative pressure is large enough, the distance between the molecules of the liquid exceeds the minimum molecular distance required to hold the liquid intact, and then the liquid breaks down and voids (cavitation bubbles) are created[2].

The medium for ultrasonication can be water, an organic solvent, or a dilute acid or base.[1]

Schematic of bench and industrial-scale ultrasonic liquid processors
Schematic of bench and industrial-scale ultrasonic liquid processors produced by Industrial Sonomechanics, LLC

Product

Ultrasonication can be used to produce:

  • Emulsions (such as nanoparticles, nanoemulsions, nanocrystals, liposomes, wax emulsions)
  • Extracts from biomass (such as polysaccharides[3], oil, anthocyanins and antioxidants[4])
  • Purified wastewater

Furthermore, ultrasonication is also utilised in following processes:

  • Adhesive thinning
  • Cells disruption
  • Degassing liquids
  • Polymer and epoxy processing
  • Ultrasound assisted oxidative desulfurisation of crude oil[5]

Post-treatment

A common application for ultrasonication is breaking down the lignocellulosic structure. The available sugars can then be converted to products such as biofuels, for example by fermentation.[1]

Technology providers

Technology comparison
Company name Country Technology category Technology name TRL Capacity [kg/h] Frequency [kHz] Power [W] Processable volume [L] Feedstock: Food waste Feedstock: Garden & park waste
Company 1 [Country HQ location] [Technology category (if different sub-categories are defined this has to be specified here, the available categories can be found on each technology page under the chapter Process and technologies)] [Technology name (the "branded name" or the usual naming from company side)] [4-9] [numeric value]
Company 2 [Country HQ location] [(if different sub-categories are defined this has to be specified here, the available categories can be found on each technology page under the chapter Process and technologies)] [Technology name (the "branded name" or the usual naming from company side)] [4-9] [numeric value]

Company 1

Ultrasonication provider
General information
Company: 21-04-27 Tech4Biowaste rect-p.png
Country:
Contact:
Webpage:
Technology and process details
Technology name: Technology category: Pre-processing (Physical processes and technologies), Post-processing (Physical processes and technologies)
TRL: Capacity: kg·h-1
Frequency: kHz Power: W
Processable volume: L Other:
Feedstock and product details
Feedstock: Product:

Hielscher Ultrasonics GmbH

Open access pilot and demo facility providers

Currently no providers have been identified.

Patents

Currently no patents have been identified.

References

  1. a b c Preeti Bhagwan Subhedar, 2016: Use of Ultrasound for Pretreatment of Biomass and Subsequent Hydrolysis and Fermentation. Biomass fractionation technologies for a lignocellulosic feedstock based biorefinery. (Ed.). Elsevier, Amsterdam, Netherlands.
  2. a b c Hugo Miguel Santos, Carlos Lodeiro, and José-Luis Capelo-Martínez, 2008: The Power of Ultrasound. Ultrasound in Chemistry: Analytical Applications. José-Luis Capelo-Martínez (Ed.). Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim, Germany.
  3. , 2017-09-01: Polysaccharides from macroalgae: Recent advances, innovative technologies and challenges in extraction and purification. Food Research International, Vol. 99, 1011–1020. doi: https://doi.org/10.1016/j.foodres.2016.11.016
  4. , 2013-09-01: Effect of ultrasound frequency on antioxidant activity, total phenolic and anthocyanin content of red raspberry puree. Ultrasonics Sonochemistry, Vol. 20, (5), 1316–1323. doi: https://doi.org/10.1016/j.ultsonch.2013.01.020
  5. , 2020-05-01: Study on ultrasound-assisted oxidative desulfurization for crude oil. Ultrasonics Sonochemistry, Vol. 63, 104946. doi: https://doi.org/10.1016/j.ultsonch.2019.104946